The game is built around the DX10 API IIRC so unless you want to run one of the unofficial ports of DX10 to XP I would say yes. Just loaded Win7 Professional 64-bit myself over XP, and I've had no problems with it at all, once it's set up there's very little difference anyway, just make sure you turn UAC to never notify and be aware that you can't have the classic Start Menu style any more.
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