Yes, you would always get the same results from a specific combination from that saved game (unless you go to a different location/map since that in itself changes the combination); a simple reloading of the game and use of the scroll will not change the unit type you get.
Btw, I forgot to address Elwin's other question: you only get Black Knight from Call of Death since BKs are level 4 and Call Colossus only generates level 5 units.
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