Well, the spawn places are random, but there have been demonologists on Bolo, Verona, Dersu, Shatterra and nameless in my games.
As for the unit, they can spawn various demons to help them. Their stats are (looking at the guide):
Race: Neutrals
Leadership: 210
Attack: 30
Defense: 25
Initiative: 6
Speed: 2
Crit: 12%
Damage (close combat): 9-10 phys
Damage (ranged): 12-14 fire
Damage vs. Demons: 18-21 magic
Health: 160
Resists: 25% fire, 25% magic
Shooting range: 4 squares
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